Which President has a capital city in Africa named after him?

Answer: James Monroe

 Monrovia is named in honor of U.S. President James Monroe, a prominent supporter of the colonization of Liberia and the American Colonization Society. Along with Washington, D.C., it is one of two national capitals to be named after a U.S. President.

In 1816, with the aim of establishing a self-sufficient colony for emancipated American survivors of slavery, something that had already been accomplished in Freetown, the first settlers arrived in Africa from the United States. They landed at Sherbro Island in present-day Sierra Leone.

In January 7, 1822, a second ship rescued the settlers and took them to Cape Mesurado, establishing the settlement of Christopolis. In 1824, the city was renamed to Monrovia after James Monroe, then President of the United States, who was a prominent supporter of the colony in sending freed Black slaves and ex-caribbean slaves from the United States of America and Caribbean islands to Liberia and who saw it as preferable to emancipation in America. 

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